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- Title
Regioselective synthesis of vic-halo alcohols and symmetrical or unsymmetrical vic-dihalides from epoxides using triphenylphosphine – N-halo imides.
- Authors
Iranpoor, Nasser; Firouzabadi, Habib; Azadi, Roya; Ebrahimzadeh, Farzaneh
- Abstract
A simple, novel, and highly regioselective cleavage of epoxides into vicinal halo alcohols and symmetrical or unsymmetrical dihalides is described using different stoichiometries of triphenylphosphine (PPh3) and N-halo succinimide (NXS) or N-halo saccharine (NXSac).
- Subjects
EPOXY compounds; PHYSICAL &; theoretical chemistry; ALCOHOLS (Chemical class); STOICHIOMETRY; ORGANIC synthesis; SUCCINIMIDES; IMIDES
- Publication
Canadian Journal of Chemistry, 2006, Vol 84, Issue 1, p69
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/V05-261