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- Title
Synthesis and aminolysis of N-(bicyclo[2.2.1]hept-5-en- endo-2-ylmethyl)- N-(oxiran-2-ylmethyl)(7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonamide.
- Authors
Pal'chikov, V.; Prid'ma, S.; Kas'yan, L.
- Abstract
A new N-(oxiran-2-ylmethyl) (glycidyl) derivative has been obtained by reaction of N-(bicyclo-[2.2.1]hept-5-en- endo-2-ylmethyl)(7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonamide with epichlorohydrin. Its epoxidation and aminolysis have been studied, and the regioselectivity of these transformations has been determined by IR and H NMR spectroscopy and mass spectrometry.
- Subjects
NITROGEN spectra; NITROGEN compounds; METHYLAMINES; ETHYLENE oxide; METHANE synthesis; THERAPEUTICS
- Publication
Russian Journal of Organic Chemistry, 2014, Vol 50, Issue 9, p1312
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428014090139