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- Title
Synthesis and Spectral Properties of Unsymmetrically Substituted Mn(II) and Mn(III) Octaethylporphyrins.
- Authors
Zvezdina, S. V.; Chizhova, N. V.; Mamardashvili, N. Zh.
- Abstract
5-Mononitro-2,3,7,8,12,13,17,18-octaethylporphyrin, 5,10,15-trinitro-2,3,7,8,12,13,17,18-octaethylporphyrin, and their Cd(II) complexes were synthesized. The coordination reactions of 2,3,7,8,12,13,17,18-octaethylporphyrin and its mono- and trinitro-substituted derivatives and the metal-exchange reactions of the synthesized Cd(II) octaethylporphyrin complexes with Mn(II) chloride in DMF were investigated by spectrophotometry. The corresponding Mn(II) and Mn(III) porphyrins were obtained and identified. The kinetic parameters of the studied reactions were determined.
- Subjects
PORPHYRINS; MANGANESE porphyrins; NITRATION; CHLORIDES; METALLOPORPHYRINS; PROPERTY
- Publication
Russian Journal of Organic Chemistry, 2020, Vol 56, Issue 8, p1374
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428020080072