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- Title
Mild C-C bond cleavage in cycloalkanes by the action of new lanthanide catalysts LnCl<sub>3</sub>·3H<sub>2</sub>O·3(EtO)<sub>2</sub>AlOH.
- Authors
Bulgakov, R. G.; Karamzina, D. S.; Kuleshov, S. P.; Dzhemilev, U. M.
- Abstract
The article offers information concerning the new methods in activating thermodynamically stable nonpolar C-C bonds. Researchers found out that (Ln) in combination with (i-BU) 2AIH is a highly effective fairly efficient catalyst. The 1H and 13C NMR spectra were recorded on a JEOL FX 90Q spectrometer at 89.5 and 22.5 MHz using tetramethylsilane as internal reference and chloroform-d as solvent. The products were analyzed by GLC on a Tsvet 500M chromatograph.
- Subjects
CATALYSTS; CHEMICAL inhibitors; NUCLEAR magnetic resonance spectroscopy; SPECTRUM analysis; SPECTROMETERS; CHLOROFORM; CHROMATOGRAPHIC analysis
- Publication
Russian Journal of Organic Chemistry, 2008, Vol 44, Issue 3, p470
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428008030275