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- Title
Functional Methacryloyloxy Acetals: V. Electrophilic Addition of Carboxylic Acids to 2-Vinyloxyethyl Methacrylate.
- Authors
Vysotskaya, O. V.; Oparina, L. A.; Parshina, L. N.; Tatarinova, A. A.; Trofimov, B. A.
- Abstract
Mono- and dicarboxylic acids (acetic, methacrylic, E-crotonic, and malonic) quantitatively add to 2-vinyloxyethyl methacrylate under mild conditions (1 wt % CF3COOH, 20–60°C, 1–4 h) according to the Markownikoff rule to give the corresponding mono- and bis-adducts with high regio- and chemoselectivity. The products may be regarded as a new family of functionalized methacrylates.
- Subjects
METHYL methacrylate; METHACRYLIC acid; CARBOXYLIC acids; ORGANIC compounds; ORGANIC chemistry; PHYSICAL &; theoretical chemistry; CHEMISTRY
- Publication
Russian Journal of Organic Chemistry, 2004, Vol 40, Issue 3, p307
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1023/B:RUJO.0000034962.38627.eb