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- Title
Bifunctional Sulfonamide as Hydrogen Bonding Catalyst in Catalytic Asymmetric Reactions: Concept and Application in the Past Decade.
- Authors
Zhu, Yi‐Ren; Xu, Jie; Jiang, Hui‐Fang; Fang, Rui‐Jing; Zhang, Yan‐Jun; Chen, Lu; Sun, Chen; Xiong, Fei
- Abstract
Since the first report of bifunctional sulfonamide organocatalysts in 2004, these chiral compounds have proven to be a reliable hydrogen‐bonding catalyst and have been wildly employed in asymmetric organocatalysis due to its strong acidity and self‐aggregation‐free property. Herein, we review the application of bifunctional sulfonamide as hydrogen‐bonding catalyst after 2011, and our highlights will cover asymmetric process including aldol reaction, Michael addition, Mannich reaction, desymmetrization and cyclization.
- Subjects
HYDROGEN bonding; SULFONAMIDES; CATALYSTS; MANNICH reaction; ORGANOCATALYSIS; ALDOLS; NITROALKENES
- Publication
European Journal of Organic Chemistry, 2022, Vol 2022, Issue 45, p1
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.202201081