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- Title
A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo<sub>2</sub>O<sub>4</sub>(OH<sub>2</sub>)(DMF)(H<sup>t</sup>Bu<sub>6</sub>L)]·3DMF ([H<sub>6</sub><sup>t</sup>Bu<sub>6</sub>L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride).
- Authors
Si-Meng Wu; Xin Chen; Zhifeng Xin; Ai-Quan Jia; Qian-Feng Zhang
- Abstract
Interaction of (NH4)6Mo7O24·4H2O with tris-(3,5-di-tert-butyl-2-hydroxy-benzylidene)triaminoguanidinium chloride [H6tBu6L]Cl in DMF-H2O resulted in isolation of a neutral dinuclear Mo(VI) complex [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF. The C3-symmetric-type ligand HtBu6L is coordinated to two cis-{MoO2}2+ moieties via phenolic-oxygen, guanidine nitrogen and azomethine nitrogen atoms, and the remaining sixth coordination sites of the molybdenum centers are occupied by the oxygen atoms from the solvent molecules.
- Subjects
MOLYBDENUM; LIGANDS (Chemistry); OXYGEN; SOLVENTS; GUANIDINE
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2018, Vol 73, Issue 5, p323
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2018-0044