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- Title
Photo‐Electrochemical C−H Bond Activation of Cyclohexane Using a WO<sub>3</sub> Photoanode and Visible Light.
- Authors
Tateno, Hiroyuki; Iguchi, Shoji; Miseki, Yugo; Sayama, Kazuhiro
- Abstract
Abstract: The photo‐electrochemical C−H bond activation of cyclohexane to produce cyclohexanol and cyclohexanone (KA oil) with high partial oxidation selectivity (99 %) and high current utilization ratio (76 %) was achieved in air at room temperature at atmospheric pressure. The production rate of KA oil was accelerated by applying a bias. The incident photon to current efficiencies at 365 and 420 nm were 57 % and 24 %, respectively.
- Subjects
ELECTROCHEMISTRY; CARBON-hydrogen bonds; ACTIVATION (Chemistry); CYCLOHEXANE; TUNGSTEN oxides; ANODES; VISIBLE spectra
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 35, p11408
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201805079