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- Title
A Versatile Ligand Platform for Palladium‐ and Nickel‐Catalyzed Ethylene Copolymerization with Polar Monomers.
- Authors
Chen, Min; Chen, Changle
- Abstract
Abstract: The ability to carry out transition‐metal‐catalyzed copolymerizations of olefins with polar monomers is a great challenge in the field of olefin polymerization. Palladium has been the dominant player in this field, while its low‐cost nickel counterpart has only achieved very limited success. We report the synthesis and evaluation of a highly versatile platform based on diphosphazane monoxide ligands. Both palladium and nickel catalysts bearing these ligands mediate the copolymerization of ethylene with a number of fundamental polar monomers.
- Subjects
MONOMERS; COPOLYMERIZATION; PALLADIUM catalysts; NICKEL catalysts; ALKENES; ETHYLENE; PALLADIUM
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 12, p3148
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201711753