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- Title
Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O<sub>2</sub>CCF<sub>2</sub>SO<sub>2</sub>F) and N-Fluorobenzenesulfonimide.
- Authors
Liu, Yongan; Wu, Hao; Guo, Yong; Xiao, Ji‐Chang; Chen, Qing‐Yun; Liu, Chao
- Abstract
Presented is a novel intermolecular radical trifluoromethylfluorosulfonylation of unactivated alkenes under mild reaction conditions with good functional-group tolerance in the most atom-economic manner by using readily available Ag(O2CCF2SO2F) and N-fluorobenzenesulfonimide (NFSI). Both the trifluoromethyl and sulfonyl groups in the products originate from Ag(O2CCF2SO2F).
- Subjects
TRIFLUOROMETHYL compounds; ALKENES; SILVER nanoparticles; IMIDES; FLUOROBENZENE
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 48, p15634
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201709663