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- Title
Facile Hydrolysis and Alcoholysis of Palladium Acetate.
- Authors
Bedford, Robin B.; Bowen, John G.; Davidson, Russell B.; Haddow, Mairi F.; Seymour-Julen, Annabelle E.; Sparkes, Hazel A.; Webster, Ruth L.
- Abstract
Palladium(II) acetate is readily converted into [Pd3(μ2-OH)(OAc)5] ( 1) in the presence of water in a range of organic solvents and is also slowly converted in the solid state. Complex 1 can also be formed in nominally anhydrous solvents. Similarly, the analogous alkoxide complexes [Pd3(μ2-OR)(OAc)5] ( 3) are easily formed in solutions of palladium(II) acetate containing a range of alcohols. An examination of a representative Wacker-type oxidation shows that the Pd-OH complex 1 and a related Pd-oxo complex 4 can be excluded as potential catalytic intermediates in the absence of exogenous water.
- Subjects
PALLADIUM; SOLID state physics; ETHANOL; OXIDATION; ALKOXIDES
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 22, p6691
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201500620