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- Title
Cobalt-Catalyzed C(sp<sup>2</sup>)H Alkoxylation of Aromatic and Olefinic Carboxamides.
- Authors
Zhang, Lin ‐ Bao; Hao, Xin ‐ Qi; Zhang, Shou ‐ Kun; Liu, Zhan ‐ Jiang; Zheng, Xin ‐ Xiang; Gong, Jun ‐ Fang; Niu, Jun ‐ Long; Song, Mao ‐ Ping
- Abstract
The cobalt-catalyzed alkoxylation of C(sp2)H bonds in aromatic and olefinic carboxamides has been developed. The reaction proceeded under mild conditions in the presence of Co(OAc)2⋅4H2O as the catalyst and tolerates a wide range of both alcohols and benzamide substrates, including even olefinic carboxamides. In addition, this reaction is the first example of the direct alkoxylation of alkenes through CH bond activation.
- Subjects
ALKOXYLATION; COBALT catalysts; ALKENES; CARBOXAMIDES; BENZAMIDE; CHEMICAL bonds
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 1, p274
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201409751