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- Title
Catalytic hydrogenation of methyl 3,4-diazatricyclo-[5.2.1.0<sup>2,6</sup>]dec-4-ene-5-carboxylate.
- Authors
Gorpinchenko, V. A.; Petrov, D. V.; Khursan, S. L.; Dokichev, V. A.; Tomilov, Yu. V.
- Abstract
The hydrogenation at Raney nickel of the pyrazoline ring in methyl exo-3,4-diazatricyclo-[5.2.1.02,6]dec-4-ene-5-carboxylate takes place quantitatively with the preferential formation of the trans isomer of 5-amino- exo-3-azatricyclo[5.2.1.02,6]decan-4-one. The 3-methoxycarbonylmethyl-, 3-acetyl-, and 3-nitroso-substituted esters are not hydrogenated under these conditions.
- Subjects
HYDROGENATION; HETEROCYCLIC compounds; ORGANIC compounds; ESTERS; METHYL methacrylate
- Publication
Chemistry of Heterocyclic Compounds, 2009, Vol 45, Issue 9, p1039
- ISSN
0009-3122
- Publication type
Article
- DOI
10.1007/s10593-009-0389-1