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- Title
Synthese von Tricyclo[4.4.1.1<sup>3, 8</sup>]dodecan-4, 9-dion und Tricyclo[4.4.1.1<sup>3, 8</sup>]dodeca-4, 9-dien.
- Authors
Gerlach, H.
- Abstract
Treatment of 2, 6-bis-aminomethyladamantane-2, 6-diol (II) with nitrous acid gives tricyclo[4.4.1.13, 8]dodecane-4, 9-dione (III), which is converted into the tricyclo[4.4.1.13, 8]dodeca-4, 9-diene (V) by reduction to the corresponding diols (IV, R = H) and pyrolysis of their O-4-methylphenyl thiocarbonate O-esters. II is accessible from 2, 6-adamantanedione by reaction with diethyl aluminium cyanide and subsequent reduction with lithiumaluminium hydride. The physical properties of the new compounds including 13C NMR. spectra of III, V and tricyclo-[4.4.1.13, 8]dodecane are given.
- Publication
Helvetica Chimica Acta, 1972, Vol 55, Issue 8, p2962
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19720550828