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- Title
Branched poly(methyl methacrylates) modified by C fullerenes.
- Authors
Kurmaz, S.; Nedel'ko, V.; Perepelitsina, E.; Berezin, M.; Baturina, A.
- Abstract
The poly(methyl methacrylates) of branched structure with a covalently bonded fullerene were synthesized by three-dimensional radical polymerization of methyl methacrylate with triethylene glycol dimethacrylate or allyl methacrylate in toluene containing C. The kinetics of copolymerization of methyl methacrylate with multifunctional co-monomers in the absence of fullerene is compared with that in its presence. The physicochemical characteristics and thermal stability of the obtained copolymers are also compared. The electron spin resonance (ESR) method was applied to study the kinetics of accumulation of the fullerene radicals in the course of the (co)polymerization of methyl methacrylate.
- Subjects
FULLERENES; MOLECULAR spectra; TRIETHYLENEDIAMINE; POLYMERIZATION research; MONOMERS; METHACRYLATES; ELECTRON paramagnetic resonance
- Publication
Russian Journal of General Chemistry, 2013, Vol 83, Issue 3, p496
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S107036321303016X