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- Title
An Unusual (6, 14)-Connected Metal-Organic Framework Constructed from Two Distinct Cobalt(II) Cluster Units and a Bifunctional Organic Linker.
- Authors
Chen, Di‐Ming; Tian, Jia‐Yue; Liu, Chun‐Sen
- Abstract
A (6, 14)-connected metal-organic framework (MOF), namely [Co9(μ3-OH)2(CPT)10(HCOO)6] n ( 1) [HCPT = 4-(4-carboxyphenyl)-1, 2,4-triazole], was synthesized using custom-designed bifunctional triazolate-carboxylate organic linkers and CoII salts. The framework exhibits two types of highly connected Co3 and Co6 cluster moieties with distinct arrangement, which were generated in situ. The combination of these building units results in an unusual (6, 14)-connected structure, which has been rarely observed in MOF chemistry. This MOF was characterized by single X-ray diffraction, PXRD, and TGA. Furthermore, its magnetic properties were investigated.
- Subjects
METAL-organic frameworks; STRUCTURAL frames; COBALT spectra; FERROMAGNETIC materials; FERROMAGNETISM
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2016, Vol 642, Issue 11/12, p714
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201600114