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- Title
Asymmetric Formal [3+2] Cycloaddition Reaction of Succinaldehyde and Nitroalkene Catalyzed by Diphenylprolinol Silyl Ether.
- Authors
Umemiya, Shigenobu; Hayashi, Yujiro
- Abstract
The enantioselective domino Michael/Henry reaction of nitroalkenes with succinaldehyde was found to proceed efficiently upon using diphenylprolinol silyl ether as the organocatalyst. The reaction affords cis-disubstituted nitropentenes with excellent diastereoselectivities and enantioselectivities after treatment of the Michael product with Ac2O and pyridine.
- Subjects
RING formation (Chemistry); NITRO compounds; ENANTIOSELECTIVE catalysis; NITROALKENES; ORGANIC chemistry research
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 20, p4320
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201500623