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- Title
A Tuned Bicyclic Proazaphosphatrane for Catalytically Enhanced N-Arylation Reactions with Aryl Chlorides.
- Authors
Kim, So Han; Kim, Min; Verkade, John G.; Kim, Youngjo
- Abstract
The N-arylation of various amines with aryl chlorides proceeded in good-to-excellent yields in the presence of P[N{( p-NMe2)C6H4CH2}CH2CH2]3N ( 1e, a new electron-rich proazaphosphatrane ligand) and small amounts of Pd2(dba)3 (dba = dibenzylideneacetone). This catalytic system was also very effective for the synthesis of carbazoles.
- Subjects
ARYL chlorides; ARYLATION; LIGANDS (Chemistry); CARBAZOLE; CHEMICAL synthesis; AMINE synthesis
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 9, p1954
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201403428