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- Title
Selective Suzuki-Miyaura Monocouplings with Symmetrical Dibromoarenes and Aryl Ditriflates for the One-Pot Synthesis of Unsymmetrical Triaryls.
- Authors
Minard, Corinne; Palacio, Carole; Cariou, Kevin; Dodd, Robert H.
- Abstract
The various parameters that would permit selective Suzuki-Miyaura monocouplings of symmetrical dihaloarenes were studied. High selectivity and efficiency can be obtained for a broad range of substrates by using operationally simple conditions and widely available reagents. The 38 different examples described provide a valuable toolbox for the rapid access to unsymmetrical triaryls, as illustrated by the preparation of diarylpyridine 8, terphenyl 9, and diarylpyrrole 10.
- Subjects
SUZUKI reaction; BIOCHEMICAL substrates; CHEMICAL reagents; PALLADIUM; CHEMICAL synthesis
- Publication
European Journal of Organic Chemistry, 2014, Vol 2014, Issue 14, p2942
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201400090