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- Title
One Metal-Organic Framework Showing Two-Dimensional Sheet Structure: Synthesis, Structure, and Magnetic Property.
- Authors
Yong Hong Zhou; Zhe Yu Wang
- Abstract
Under hydrothermal condition, the reaction of 2,4-dichlorophenoxyacetic acid (2,4-DH) and 1,3-bis(4-pyridyl) propane with MnCl2⋅ gave a novel metal-organic framework (MOF), [Mn(2,4-D)2(H2O)2]n (1). This complex was characterized by IR, elemental analysis, powder X-ray diffraction, and thermogravimetry analysis. X-Ray single-crystal diffraction shows that the Mn(II) ions are bidendate bridged by carboxyl groups in the syn-anti mode, giving a two-dimensional (2D) network. Temperature-dependent magnetic studies reveal that there are weak antiferromagnetic exchange interactions between the Mn(II) ions transmitted by carboxyl groups.
- Subjects
METAL-organic framework crystallography; MANGANESE compounds; CHEMICAL synthesis; MAGNETIC properties of transition metal compounds; MAGNETIC properties of manganese compounds; DICHLOROPHENOXYACETIC acid; PYRIDYL compounds
- Publication
Bulletin of the Korean Chemical Society, 2015, Vol 36, Issue 2, p618
- ISSN
0253-2964
- Publication type
Article
- DOI
10.1002/bkcs.10120