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- Title
Construction of Optically Active Indolines by Formal [4+1] Annulation of Sulfur Ylides and N-( ortho-Chloromethyl)aryl Amides.
- Authors
Yang, Qing‐Qing; Wang, Qiang; An, Jing; Chen, Jia‐Rong; Lu, Liang‐Qiu; Xiao, Wen‐Jing
- Abstract
Get asymmetric! Asymmetric [4+1] annulation of sulfur ylides and N‐(ortho‐chloromethyl)aryl amides allowed the formation of the desired cycloadduct with moderate to high yields and enantioselectivities (see scheme). The described strategy, taking advantage of chiral sulfur ylides, represents a direct procedure to access chiral 2‐substituted indolines.
- Subjects
INDOLINE; ALKALOIDS; YLIDES; AMIDES; CHEMICAL synthesis
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 26, p8401
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201300988