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- Title
Photocatalytic Aminodecarboxylation of Carboxylic Acids.
- Authors
Lang, Simon B.; Cartwright, Kaitie C.; Welter, Richard S.; Locascio, Theresa M.; Tunge, Jon A.
- Abstract
Aminodecarboxylation of unactivated alkanecarboxylic acids has been accomplished utilizing an organic photocatalyst. This operationally simple reaction utilizes readily available carboxylic acids to chemoselectively generate reactive alkyl intermediates that are not accessible via conventional two-electron pathways. The organic radical intermediates are efficiently trapped with electrophilic diazo compounds to provide aminated alkanes.
- Subjects
CARBOXYLIC acids; ORGANIC acids; PHOTOCATALYSIS; ACIDOLYSIS; ALKANES
- Publication
European Journal of Organic Chemistry, 2016, Vol 2016, Issue 20, p3331
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201600620