We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Synthesis, Structure, and Characterization of a New Metal-Organic Framework containing Meso-Helices.
- Authors
Fan, Linlin; Chen, Haiyan; Xiao, Dongrong; Wang, Enbo
- Abstract
The new metal-organic framework [Cd(bqdc)(phen)] n ( 1) (bqdc = 2, 2′-biquinoline-4, 4′-dicarboxylate, phen = 1, 10-phenanthroline) was hydrothermally synthesized by hetero-ring carboxylate ligand and N-containing auxiliary ligand. The structure of 1 was determined by single-crystal X-ray diffraction analysis and further characterized by elemental analyses, IR spectroscopy, X-ray powder diffraction, and TG analysis. Single-crystal X-ray structural analysis shows that complex 1 is an infinite two-dimensional framework containing aesthetic meso-helix. These two-dimensional coordination networks are interconnected through aromatic π-π stacking and C-H ···O hydrogen bonding interactions to afford a 6-connected (412.63) three-dimensional supramolecular architecture. Furthermore, the photoluminescent property of complex 1 was studied.
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2013, Vol 639, Issue 3/4, p558
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201200474