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- Title
Experimental optimization, design synthesis, and up-conversion luminescence properties of Sr<sub>2</sub>GdTaO<sub>6</sub>: Er<sup>3+</sup>/Yb<sup>3+</sup> high color purity.
- Authors
Liu, Shengyi; Gao, Duan; Wang, Li; Song, Wenbin; Zhang, Zhiliang; Wang, Shitao; Zhu, Ying; Du, Peilin
- Abstract
Laser illumination is considered to be a revolution of new lighting technology due to its high efficiency and pure color. Similar to the white Light Emitting Diode (LED), phosphor convertor is also a necessary component to generate light in laser illumination technology. In order to improve the performance of laser, designing and optimizing phosphor with high color purity is an effective method. In our study, the pure-red Sr2GdTaO6:Er3+/Yb3+ powders were synthesized and optimized using a high-temperature solid-phase method. The phosphor structure of the obtained phosphors was analyzed through X-ray diffraction (XRD), confirming all products are Sr2GdTaO6 polycrystalline powders. Theoretical models, optimized through experimental design, established regression equations correlating Er3+/Yb3+ doping concentrations with luminescence intensity. Leveraging a genetic algorithm, the optimal solutions for the equations were calculated, resulting in Er3+ and Yb3+ doping concentrations of 4.99% and 24.85% under 980 nm laser excitation and 4.95% and 23.19% under 1550 nm laser excitation, respectively. Under the same conditions, the up-conversion fluorescence emission spectra of the samples were measured, revealing strong green and red emissions with peaks at 550 nm, 563 nm, and 663 nm, corresponding to transitions from 2H11/2 → 4I15/2, 4S3/2 → 4I15/2, and 4F9/2 → 4I15/2 energy levels. For the optimal samples at 980 nm and 1550 nm, the relationship between up-conversion luminescence and laser operating current was explored, indicating that the up-conversion luminescence in these two cases is a two-photon and three-photon process, respectively. The up-conversion luminescence mechanism was analyzed and discussed in detail. Additionally, the relationship between up-conversion fluorescence and temperature was investigated for the optimal samples, revealing excellent temperature-sensing characteristics for up-conversion emissions excited by both 980 nm and 1550 nm lasers. The CIE coordinates (0.5986, 0.3973) and (0.7089, 0.2910) of the optimal sample were calculated under excitation at 980 nm and 1550 nm wavelengths.
- Subjects
LUMINESCENCE; LIGHT emitting diodes; ENERGY levels (Quantum mechanics); LUMINESCENCE spectroscopy; FLUORESCENCE spectroscopy; GENETIC algorithms; DOPING agents (Chemistry)
- Publication
Journal of Materials Science: Materials in Electronics, 2024, Vol 35, Issue 18, p1
- ISSN
0957-4522
- Publication type
Article
- DOI
10.1007/s10854-024-12902-z