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- Title
Study of Acidic (Tetracaprolactam) Dodecamolybdosilicate of the Composition (C<sub>6</sub>H<sub>11</sub>NO)<sub>4.5</sub>Н<sub>4</sub>[SiМо<sub>12</sub>O<sub>40</sub>].
- Authors
Stepnova, A. F.; Kaziev, G. Z.; Dorovatovskii, P. V.; Zubavichus, Ya. V.; Quiñones, Saúl Holguín; Van Bang, Nguen; Khrustalev, V. N.
- Abstract
New caprolactam dodecamolybdosilicate of the composition (C6H11NO)4.5Н4[SiМо12O40] (I) is synthesized. Chemical and crystallographic analyses, NMR and IR spectroscopic studies are performed. Compound I is found to crystallize in the monoclinic system with the space group P21/n. Unit cell parameters are: a = 19.945(4) Å, b = 13.340(3) Å, c = 28.110(6) Å, β = 110.75(3)°, ρcalc = 2.232 g/cm3, М = 2350.63, Z = 4, V = 6994(3) Å3.
- Subjects
CAPROLACTAM; TRANSITION metal compounds synthesis; HETEROPOLY acids; MONOCLINIC crystal system; INFRARED spectroscopy
- Publication
Journal of Structural Chemistry, 2018, Vol 59, Issue 3, p627
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476618030174