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- Title
Expanding Boundaries: N<sub>2</sub> Cleavage and Functionalization beyond Early Transition Metals.
- Authors
Bezdek, Máté J.; Chirik, Paul J.
- Abstract
Early transition metals are well known to catalyze the cleavage and functionalization of N2. In this Highlight, recent work showing that a rhenium catalyst is also capable of carrying out this difficult task is summarized, and a synthetic cycle for the stoichiometric incorporation of atmospheric N2 into acetonitrile is presented.
- Subjects
NITROGEN fixation; NITROGEN spectra; SCISSION (Chemistry); CHEMICAL reactions; NITRILE synthesis; TRANSITION metals spectra
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 28, p7892
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201603142