We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Synthesis and Characterization of Ni(II), Cu(II) , Co(II) , Cr(II) and Fe(II) Metal Complexes of New 1,3,4-Triazole Derivative.
- Authors
Naser, Hameedi N.
- Abstract
A Schiff base of 1,3,4-triazole derivative have been synthesized by the reaction between 5-(4-methylphenyl)-1,3,4-oxadiazole-2-thiol and hydrazine in the presence pyridine as catalyst to yield the 4- amino-5-(4-methylphenyl)-4H-1,2,4-triazole-3-thiol which was treated with aromatic aldehyde to gave five member heterocyclic ring schiff base called 5-(4-methylphenyl)-4- [(pyridin-2-ylmethylidene)amino]-4H-1,2,4-triazole-3-thiol as didentate ligand. The last compound reacted with hydrated metal chlorides NiCl2, CuCl2, CoCl3,CrCl3 and FeCl3 in presence of ethanol as solvent to yield 1,3,4-triazole complexes. The structures of synthesized ligand and their complexes have been established on the basis of their spectral FTIR, Mass,1H-NMR, elemental analysis C,H,N as well as Molar conductance .The purity of the compounds was confirmed by TLC.
- Subjects
COPPER ions; NICKEL isotopes; METAL complexes; TRIAZOLE derivatives; SCHIFF bases
- Publication
Iraqi National Journal Of Chemistry, 2017, Vol 17, Issue 1, p1
- ISSN
2223-6686
- Publication type
Article
- DOI
10.22317/iqnjc.06201702