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Ferric Heme Superoxide Reductive Transformations to Ferric Heme (Hydro)Peroxide Species: Spectroscopic Characterization and Thermodynamic Implications for H‐Atom Transfer (HAT).
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- Angewandte Chemie, 2021, v. 133, n. 11, p. 5972, doi. 10.1002/ange.202013791
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Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O−H and C−H Substrates.
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- Angewandte Chemie, 2019, v. 131, n. 49, p. 17736, doi. 10.1002/ange.201908471
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Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O<sub>2</sub> and NO and Mechanistic Insights into Metal‐Mediated Peroxynitrite Decomposition.
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- Angewandte Chemie, 2019, v. 131, n. 32, p. 11052, doi. 10.1002/ange.201904672
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Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes.
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- Angewandte Chemie, 2016, v. 128, n. 40, p. 12591, doi. 10.1002/ange.201605705
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Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes.
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- Angewandte Chemie International Edition, 2016, v. 55, n. 40, p. 12403, doi. 10.1002/anie.201605705
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Observation of a Cu<sup>II</sup><sub>2</sub>(μ-1,2-peroxo)/Cu<sup>III</sup><sub>2</sub>(μ-oxo)<sub>2</sub> Equilibrium and its Implications for Copper-Dioxygen Reactivity.
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- Angewandte Chemie International Edition, 2014, v. 53, n. 19, p. 4935, doi. 10.1002/anie.201402166
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Observation of a Cu<sup>II</sup><sub>2</sub>(μ-1,2-peroxo)/Cu<sup>III</sup><sub>2</sub>(μ-oxo)<sub>2</sub> Equilibrium and its Implications for Copper-Dioxygen Reactivity.
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- Angewandte Chemie, 2014, v. 126, n. 19, p. 5035, doi. 10.1002/ange.201402166
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- Article
Spectroscopic Elucidation of a New Heme/Copper Dioxygen Structure Type: Implications for O⋅⋅⋅O Bond Rupture in Cytochrome c Oxidase.
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- Angewandte Chemie, 2012, v. 124, n. 1, p. 172, doi. 10.1002/ange.201104080
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- Article
Eins ist zu wenig, drei sind zuviel: Oxidation von Methan an Dikupferzentren.
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- Angewandte Chemie, 2010, v. 122, n. 38, p. 6864, doi. 10.1002/ange.201003403
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- Article
Bioinorganic chemistry: Model offers intermediate insight.
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- Nature, 2010, v. 463, n. 7278, p. 168, doi. 10.1038/463168a
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Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach.
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- Chemistry - A European Journal, 2017, v. 23, n. 72, p. 18314, doi. 10.1002/chem.201705066
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Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu<sub>2</sub>O<sub>2</sub> Core with Unexpected Structure and Reactivity.
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- Chemistry - A European Journal, 2016, v. 22, n. 15, p. 5133, doi. 10.1002/chem.201600551
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- Article
Ferric Heme Superoxide Reductive Transformations to Ferric Heme (Hydro)Peroxide Species: Spectroscopic Characterization and Thermodynamic Implications for H‐Atom Transfer (HAT).
- Published in:
- Angewandte Chemie International Edition, 2021, v. 60, n. 11, p. 5907, doi. 10.1002/anie.202013791
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- Publication type:
- Article
Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O−H and C−H Substrates.
- Published in:
- Angewandte Chemie International Edition, 2019, v. 58, n. 49, p. 17572, doi. 10.1002/anie.201908471
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- Publication type:
- Article
Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O<sub>2</sub> and NO and Mechanistic Insights into Metal‐Mediated Peroxynitrite Decomposition.
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- Angewandte Chemie International Edition, 2019, v. 58, n. 32, p. 10936, doi. 10.1002/anie.201904672
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- Article
A μ-η2:η2-Disulfide Dicopper(II) Complex from Reaction of S8 with a Copper(I) Precursor: Reactivity of the Bound Disulfur MoietyK. D. Karlin is grateful to the US National Institute of Health (NIH, GM 28962) for financial support of the research. M. E. Helton acknowledges support from the NIH for a postdoctoral fellowship. We also acknowledge Dr. Andreas Heutling (Boston University) for carrying out preliminary studies.
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- Angewandte Chemie, 2006, v. 118, n. 7, p. 1156, doi. 10.1002/ange.200503216
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- Article
Cover Picture: Synthesis and Characterization of PY2- and TPA-Appended Diphenylglycoluril Receptors and Their Bis-CuI Complexes (Eur. J. Org. Chem. 10/2006).
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- European Journal of Organic Chemistry, 2006, v. 2006, n. 10, p. 2241, doi. 10.1002/ejoc.200690020
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Synthesis and Characterization of PY2- and TPA-Appended Diphenylglycoluril Receptors and Their Bis-CuI Complexes.
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- European Journal of Organic Chemistry, 2006, v. 2006, n. 10, p. 2281, doi. 10.1002/ejoc.200500865
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- Article
A μ-η2:η2-Disulfide Dicopper(II) Complex from Reaction of S8 with a Copper(I) Precursor: Reactivity of the Bound Disulfur MoietyK. D. Karlin is grateful to the US National Institute of Health (NIH, GM 28962) for financial support of the research. M. E. Helton acknowledges support from the NIH for a postdoctoral fellowship. We also acknowledge Dr. Andreas Heutling (Boston University) for carrying out preliminary studies.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 7, p. 1138, doi. 10.1002/anie.200503216
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- Article
Bioinorganic chemistry: Redox control of oxoiron(IV).
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- Nature Chemistry, 2010, v. 2, n. 9, p. 711, doi. 10.1038/nchem.813
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- Article
Electron-Transfer Reduction of Dinuclear Copper Peroxo and Bis-μ-oxo Complexes Leading to the Catalytic Four-Electron Reduction of Dioxygen to Water.
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- Chemistry - A European Journal, 2012, v. 18, n. 4, p. 1084, doi. 10.1002/chem.201103215
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- Article
A peroxynitrite complex of copper: formation from a copper–nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration.
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- Journal of Biological Inorganic Chemistry (JBIC), 2009, v. 14, n. 8, p. 1301, doi. 10.1007/s00775-009-0575-8
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Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu<sub> n</sub>-O<sub>2</sub> structure and subsequent reactivity.
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- Journal of Biological Inorganic Chemistry (JBIC), 2004, v. 9, n. 6, p. 669, doi. 10.1007/s00775-004-0578-4
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Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms.
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- Israel Journal of Chemistry, 2016, v. 56, n. 9/10, p. 738, doi. 10.1002/ijch.201600025
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- Article
Spectroscopic Elucidation of a New Heme/Copper Dioxygen Structure Type: Implications for O⋅⋅⋅O Bond Rupture in Cytochrome c Oxidase.
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- Angewandte Chemie International Edition, 2012, v. 51, n. 1, p. 168, doi. 10.1002/anie.201104080
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- Article
One is Lonely and Three is a Crowd: Two Coppers Are for Methane Oxidation.
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- Angewandte Chemie International Edition, 2010, v. 49, n. 38, p. 6714, doi. 10.1002/anie.201003403
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- Article
Structural Studies of Copper(I) Complexes of Amyloid-β Peptide Fragments: Formation of Two-Coordinate Bis(histidine) Complexes.
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- Angewandte Chemie International Edition, 2008, v. 47, n. 47, p. 9084, doi. 10.1002/anie.200803908
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Reactions of a Copper(II) Superoxo Complex Lead to CH and OH Substrate Oxygenation: Modeling Copper-Monooxygenase CH Hydroxylation.
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- Angewandte Chemie International Edition, 2008, v. 47, n. 1, p. 82, doi. 10.1002/anie.200704389
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- Article