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- Title
Catalyst‐ and Light‐free S−H Insertion between Phosphorodithioic Acids and Diazo Compounds: Rapid Access to Dialkylphosphorodithioates.
- Authors
Huang, Meiling; Ye, Zi; Xu, Weici; Xu, Ming‐Hua
- Abstract
A catalyst‐ and light‐free S−H insertion of phosphorodithioic acids with diazo compounds has been developed, in which phosphorodithioic acid acts not only as an acid promoter but also as a nucleophile. This protocol features fast reaction rate, broad substrate scope, mild conditions, and simple operation, providing a cost‐effective and general approach to diverse phosphorodithioates.
- Subjects
DIAZO compounds; ACIDS
- Publication
Asian Journal of Organic Chemistry, 2023, Vol 12, Issue 7, p1
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.202300053