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- Title
Crystal structure and luminescence properties of a new dinuclear bismuth(III) coordination polymer containing three types of ligands.
- Authors
Feng, Yu-Quan; Zhong, Zhi-Guo; Wang, Hong-Wei; Xing, Zheng-Zheng; Wang, Lu
- Abstract
A new dinuclear bismuth(III) coordination polymer {[Bi(H2O)]2(C7H3NO4)2(C12H8N2)2(N3)2·2H2O}<italic>n</italic> (<bold>1</bold>) containing three types of ligands has been synthesized using a solvothermal method and characterized by infrared (IR) spectroscopy, energy-dispersive X-ray spectroscopy, and X-ray single-crystal structural analysis. The compound can be viewed as a three-dimensional supramolecular network that is constructed by Bi3+ cations, N3− anions, pyridine-2,5-dicarboxylate (2,5-pdc2−), and 1,10-phenanthroline (phen) ligands. Moreover, the luminescence properties, quantum yield, luminescence decay, and thermal stabilities of <bold>1</bold> were also investigated.
- Subjects
CRYSTAL structure; COORDINATION polymers; BISMUTH compounds; LUMINESCENCE; LIGANDS (Chemistry)
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2018, Vol 73, Issue 3/4, p155
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2017-0134