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- Title
Controlled Memristic Behavior of Metal-Organic Framework as a Promising Memory Device.
- Authors
Li, Lei
- Abstract
Metal-organic frameworks (MOFs) have attracted considerable interests for sensing, electrochemical, and catalytic applications. Most significantly, MOFs with highly accessible sites on their surface have promising potential for applications in high-performance computing architecture. In this paper, Mg-MOF-74 (a MOF built of Mg(II) ions linked by 2,5-dioxido-1,4-benzenedicarboxylate (DOBDC) ligands) and graphene oxide composites (Mg-MOF-74@GO) were first used as an active layer to fabricate ternary memory devices. A comprehensive investigation of the multi-bit data storage performance for Mg-MOF-74@GO composites was discussed and summarized. Moreover, the structure change of Mg-MOF-74@GO after introducing GO was thoroughly studied. The as-fabricated resistive random access memory (RRAM) devices exhibit a ternary memristic behavior with low SET voltage, an RHRS/RIRS/RLRS ratio of 103:102:1, superior retention (>104 s), and reliability performance (>102 cycles). Herein, Mg-MOF-74@GO composite films in constructing memory devices were presented with GO-mediated ternary memristic properties, where the distinct resistance states were controlled to achieve multi-bit data storage. The hydrogen bonding system and defects of GO adsorbed in Mg-MOF-74 are the reason for the ternary memristic behavior. The charge trapping assisted hopping is proposed as the operation mechanism, which is further confirmed by XRD and Raman spectra. The GO-mediated Mg-MOF-74 memory device exhibits potential applications in ultrahigh-density information storage systems and in-memory computing paradigms.
- Subjects
NONVOLATILE random-access memory; METAL-organic frameworks; COMPUTER storage devices; DATA warehousing; MEMORY; RAMAN spectroscopy
- Publication
Nanomaterials (2079-4991), 2023, Vol 13, Issue 20, p2736
- ISSN
2079-4991
- Publication type
Article
- DOI
10.3390/nano13202736