We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Theoretical study of product polarization of O(<sup>1</sup>D) + HCl( v = 0; j = 0) → ClO + H and its isotope exchange reaction.
- Authors
Mei Hua Ge; Huan Yang; Yujun Zheng
- Abstract
O(1D) + HCl(v = 0; j = 0) → ClO + H and its isotope exchange reaction O(1D) + DCl(v = 0; j = 0) → ClO + D are studied in the collision energy range 14.0-20.0 kcal/mol based on the potential energy surface 1A' state. Reaction probabilities, integral cross sections, the two angular distribution functions (concerning the initial/final velocity vector, and the product rotational momentum vector), and the product rotational alignment parameters are calculated as a function of the collision energy for the two reactions. The four generalized polarization dependent differential cross sections are presented to manifest the polarization characters. Also, the effect of the collision energy and the kinetic isotope effect are studied.
- Subjects
HYDROGEN chloride; KINETIC isotope effects; ISOTOPE exchange reactions; CHEMICAL kinetics; DIFFERENTIAL cross sections; ACID deposition
- Publication
Canadian Journal of Chemistry, 2015, Vol 93, Issue 11, p1290
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/cjc-2015-0288