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- Title
Dibromometallyl‐iron complexes generated by the recombination of an alumanyl‐iron complex with EBr<sub>3</sub> (E = Al, Ga).
- Authors
Yanagisawa, Tatsuya; Mizuhata, Yoshiyuki; Tokitoh, Norihiro
- Abstract
The first dibromoalumanyl‐iron complex [Br2Al–FeCp(CO)2] was synthesized by the reaction of monobromoalumanyl‐iron complex bearing a bulky substituent on aluminum atom with AlBr3, whose structure was determined by the X‐ray crystallographic analysis and the NMR measurement. The reactions monobromoalumanyl‐iron complex with GaBr3 show that these reactions would proceed by the mutual recombination of substituents.
- Subjects
CHEMICAL reactions; NUCLEAR magnetic resonance; X-ray diffraction; HYDROGEN content of iron; TRANSITION metals
- Publication
Heteroatom Chemistry, 2018, Vol 29, Issue 5/6, pN.PAG
- ISSN
1042-7163
- Publication type
Article
- DOI
10.1002/hc.21465