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- Title
Synthesis, Structure, and Luminescent Properties of a Cadmium(II) Supramolecular Coordination Complex.
- Authors
Chen, Y. M.; Peng, F.; Zhang, Q. C.; Huang, L. C.; Zhang, W. J.
- Abstract
A new supramolecular complex [Cd(dcbpy)(im)2(H2O)2] · 3H2O (H2dcbpy = 4,4'-dicarboxy-2,2'-bipyridine, im = imidazole) has been prepared under hydrothermal conditions. Its crystal structure is determined with single crystal X-ray diffraction. Cd2+ atom is six-coordinated by one dcbpy ligand, two imidazole and two water molecules. Each [Cd(dcbpy)(im)2(H2O)2] unit is connected to neighboring units through intermolecular O–H···O hydrogen bonds to form a three-dimensional supramolecular network structure. A topology method has been used to simplify the network. The stability and luminescent properties of the complex obtained have been investigated.
- Subjects
CADMIUM; IMIDAZOLES; SINGLE crystals; HYDROGEN bonding; CRYSTAL structure; X-ray diffraction
- Publication
Crystallography Reports, 2019, Vol 64, Issue 7, p1094
- ISSN
1063-7745
- Publication type
Article
- DOI
10.1134/S1063774519070046