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- Title
Natural Cinnamic Acid Derivatives: A Comprehensive Study on Structural, Anti/Pro-Oxidant, and Environmental Impacts.
- Authors
Gryko, Kamila; Kalinowska, Monika; Ofman, Piotr; Choińska, Renata; Świderski, Grzegorz; Świsłocka, Renata; Lewandowski, Włodzimierz
- Abstract
Cinnamic acid (CA), p-coumaric acid (4-hydroxycinnamic acid, 4-HCA), caffeic acid (3,4-vdihydroxycinnamic acid, 3,4-dHCA), and 3,4,5-trihydroxycinnamic acid (3,4,5-tHCA) were studied for their structural, anti-/pro-oxidant properties and biodegradability. The FT-IR, FT-Raman, UV/Vis, 1H and 13C NMR, and quantum chemical calculations in B3LYP/6-311++G** were performed to study the effect on number and position of hydroxyl group in the ring on the molecular structure of molecules. The antioxidant properties of the derivatives were examined using DPPH● and HO● radicals scavenging assays, ferric ion reducing antioxidant power (FRAP), cupric reducing antioxidant capacity (CUPRAC), inhibition of linoleic acid oxidation, as well as the biological antioxidant assay with Saccharomyces cerevisiae. Moreover, the pro-oxidant activity of compounds in Trolox oxidation assay was estimated. The effect of the derivatives on environment on the basis of increasing the carbon and nitrogen compounds transformation processes occurring in biological wastewater treatment was studied.
- Subjects
CINNAMIC acid derivatives; NITROGEN compounds; CARBON compounds; CAFFEIC acid; MOLECULAR structure; HYDROXYCINNAMIC acids; PHENOLIC acids; CINNAMIC acid
- Publication
Materials (1996-1944), 2021, Vol 14, Issue 20, p6098
- ISSN
1996-1944
- Publication type
Article
- DOI
10.3390/ma14206098