We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Electrocatalytic O<sub>2</sub> Reduction at a Bio-inspired Mononuclear Copper Phenolato Complex Immobilized on a Carbon Nanotube Electrode.
- Authors
Gentil, Solène; Serre, Doti; Philouze, Christian; Holzinger, Michael; Thomas, Fabrice; Le Goff, Alan
- Abstract
An original copper-phenolate complex, mimicking the active center of galactose oxidase, featuring a pyrene group was synthesized. Supramolecular pi-stacking allows its efficient and soft immobilization at the surface of a Multi-Walled Carbon Nanotube (MWCNT) electrode. This MWCNT-supported galactose oxidase model exhibits a 4 H+/4 e− electrocatalytic activity towards oxygen reduction at a redox potential of 0.60 V vs. RHE at pH 5.
- Subjects
ELECTROCATALYSIS; OXYGEN reduction; COPPER compounds synthesis; MULTIWALLED carbon nanotube synthesis; SUPRAMOLECULAR chemistry; GALACTOSE oxidase
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 7, p2563
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201509593