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- Title
The Theoretical Description of Cathodic Deposition of New Conducting Polymer Composite, Assisted by a Perrhenate of a Novel Triazolic Derivative.
- Authors
Tkach, Volodymyr V.; Kushnir, Marta V.; Storoshchuk, Nataliia M.; Parchenko, Volodymyr V.; Aksyonova, Ilona I.; Odyntsova, Vira M.; Luganska, Olga V.; Yagodynets, Petro I.
- Abstract
The theoretical description of a new sandwich-like rhenium-based polymer composite cathodic electrodeposition has been given. The cathodic process is realized by perrhenate-ion electrochemical reduction to rhenium (IV) oxide, acting as an in situ formed oxidant for 3,4-dimethoxypyrrole polymerization. It is shown that the polymer deposition in this system is realized by more efficient manner than during the direct electropolymerization. The polymer composite has to have a well-developed morphology and enhanced conductivity by sandwich-like structure. The oscillatory behavior, in this case, is also possible, being caused by the DEL influences on both electrochemical and chemical stages of the process.
- Subjects
CONDUCTING polymer composites; CHEMICAL processes; ELECTROLYTIC reduction; ELECTROPOLYMERIZATION
- Publication
Orbital: The Electronic Journal of Chemistry, 2020, Vol 12, Issue 2, p34
- ISSN
1984-6428
- Publication type
Article
- DOI
10.17807/orbital.v12i2.1193