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- Title
Oxidation of menthone oxothiolane.
- Authors
Timshina, A. V.; Rubtsova, S. A.; Alekseev, I. N.; Kodess, M. I.; Mamochkina, E. G.; Slepukhin, P. A.; Kuchin, A. V.
- Abstract
meta-Chloroperoxybenzoic acid ( m-ClPBA) was shown to be an oxidant for two stereoisomers of menthone oxothiolane. The effect of steric factors on the ability to oxidize the sulfide group was found. Oxidation of (5 S,6 S,9 R)-6-isopropyl-9-methyl-1-oxo-4-thiaspiro[4.5]-decane to the sulfone was prevented by the steric proximity of an isopropyl group to the S atom in the oxothiolane ring.
- Subjects
OXIDATION; MENTHONE; SULFIDE crystals; SULFONES; STEREOISOMERS; CHEMICAL reactions; MOLECULAR structure; ASYMMETRIC synthesis
- Publication
Chemistry of Natural Compounds, 2008, Vol 44, Issue 6, p728
- ISSN
0009-3130
- Publication type
Article
- DOI
10.1007/s10600-009-9191-7