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- Title
Rhodium‐Catalyzed N‐Arylation Addition of Arylboronic Acids to Ketimines.
- Authors
Qian, Xue‐Wei; Sun, Xing‐Wen
- Abstract
Comprehensive Summary: Herein, we report rhodium catalyzed N‐arylation via addition of arylboronic acids to electron‐deficient α‐iminoesters which can be prepared in high efficiency by using easily accessible β‐carbonyl esters. The reaction is highly regiospecific to achieve the N‐aryl addition efficiently with up to 99% yield under mild conditions. The corresponding product can be further efficiently converted into indoles and a series of other important building blocks.
- Subjects
RHODIUM; INDOLE compounds; UMPOLUNG; INDOLE; ESTERS; IMINES
- Publication
Chinese Journal of Chemistry, 2024, Vol 42, Issue 18, p2243
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.202400208