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- Title
Molecular interaction studies of the volumetric behaviour of binary liquid mixtures containing alcohols.
- Authors
Djordjević, Bojan D.; Radović, Ivona R.; Kijevčanin, Mirjana Lj.; Tasić, Aleksandar Ž.; Šerbanović, Slobodan P.
- Abstract
An attempt has been made to relate the volumetric effects involved in the binary mixtures of normal and branched alcohols and various components (aromatics, halo and nitroaromatics and haloaliphatics) with the molecular interactions of unlike molecules. This review is a condensation of research activities developed in recent years as results of a better understanding of volumetric behaviour and a stronger insight into the complex structure of those mixtures. The influence of important contributions of a physical, chemical and geometrical nature that change excess molar volume, VE (positive, sigmoidal, negative) is considered and explained in detail. It appears that the balance between these contributions is quite sensitive to the behaviour of the alcohol molecules in contact with the chosen compounds.
- Subjects
ALCOHOL; AROMATICITY; MOLECULAR structure; MOLECULES; MIXTURES; MOLECULAR volume; NITROAROMATIC compounds
- Publication
Journal of the Serbian Chemical Society, 2009, Vol 74, Issue 5, p477
- ISSN
0352-5139
- Publication type
Article
- DOI
10.2298/JSC0905477D