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- Title
New Method for the Synthesis of Terphenyl and Its Derivatives.
- Authors
Chukhadzyan, E. O.; Ayrapetyan, L. V.
- Abstract
This review is intended to elucidate the structure, biological activity, and use of various strategies for the synthesis of terphenyl and its derivatives from amines obtained by the Stevens rearrangement. The amine transformation is a domino reaction, including β-elimination of secondary amine with the formation of a conjugated dienyne, which forms a cyclic allene intermediate by an electrocyclic reaction. The subsequent 1,3- or 1,5-hydride shift rapidly produces the final compound.
- Subjects
TERPHENYL; SECONDARY amines; AMINE derivatives; ALLENE; AMINES
- Publication
Russian Journal of Organic Chemistry, 2023, Vol 59, Issue 10, p1730
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428023100081