We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Long-lived 9-cyano-9,10-dimethylphenanthrenyl cation. Migration of cyano group in carbocations.
- Authors
Bushmelev, V.; Genaev, A.; Sal'nikov, G.; Shubin, V.
- Abstract
Long-lived 9-cyano-9,10-dimethylphenanthrenyl cation was generated in superacidic medium, and its structure was determined by H and C NMR spectroscopy. The energy barrier to 1,2-shift of the cyano group in 9-cyano-9,10-dimethylphenanthrenyl cation was estimated by NMR and DFT calculations.
- Subjects
CARBOCATIONS; NUCLEAR magnetic resonance spectroscopy; DENSITY functionals; ELECTROPHILES; ATOMS; SUBSTITUTION reactions; HYDROGEN bonding; CARBON
- Publication
Russian Journal of Organic Chemistry, 2011, Vol 47, Issue 7, p1050
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S107042801107013X