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- Title
Effect of the Reaction Products on the Rate of Oxidation of Crotonaldehyde.
- Authors
Fedevich, O. E.; Levush, S. S.; Fedevich, E. V.; Kit, Yu. V.
- Abstract
Study of the oxidation of crotonaldehyde revealed an appreciable inhibitory effect of the products on the process. Analysis of the kinetic data obtained over a wide range of reaction conditions (c0 1.5-3.3 M, pO2 1-16 atm, T 293-309 K) showed that the overall oxidation process (with account taken of the inhibitory effect of the products) is described by the equation: WCA = k*apcCA (pO2)0.6 (1 + 0.17ΔcτCA)-1, where k*ap is the apparent rate constant, and ΔcτCA is the decrease of the aldehyde concentration by a moment τ.
- Subjects
OXIDATION; ASYNCHRONOUS transfer mode; ORGANIC compounds; FRETTING corrosion; NITRIFICATION; OXIDIZING agents
- Publication
Russian Journal of Organic Chemistry, 2003, Vol 39, Issue 1, p29
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1023/A:1023482226774