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- Title
Front Cover: Pd/Zn Co‐catalyzed Asymmetric Ring‐Opening Reactions of Aza/Oxabicyclic Alkenes with Oximes (Asian J. Org. Chem. 1/2019).
- Authors
Shen, Guoli; Khan, Ruhima; Yang, Fan; Yang, Yong; Pu, Dongdong; Gao, Yang; Zhan, Yong; Luo, Yang; Fan, Baomin
- Abstract
An asymmetric ring‐opening reaction of aza/oxabicyclic alkenes with aromatic oximes was established. The reaction was co‐catalyzed by Pd(OAc)2 and zinc triflate with (R)‐DIFLUORPHOS as the chiral ligand, affording cis‐stereoselective asymmetric ring‐opening products. A synthetic application of this method has been demonstrated by transforming the products to chiral amino alcohols and chiral vicinal diols. More information can be found in the Communication by Yong Yang, Baomin Fan et al. on page 97 in Issue 1, 2019 (DOI: 10.1002/ajoc.201800569).
- Subjects
PALLADIUM catalysts; RING-opening reactions; ALKENES
- Publication
Asian Journal of Organic Chemistry, 2019, Vol 8, Issue 1, p1
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.201800696