We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Recent Advances and Perspectives of Transition Metal-Catalyzed Asymmetric Fluorination Reactions.
- Authors
Chen, Chaohuang; Fu, Liang; Chen, Pinhong; Liu, Guosheng
- Abstract
The synthesis of fluorine-containing molecules has received intensive attention in recent years due to the great value of fluorides, however, the transition metal-catalyzed asymmetric construction of C-F bonds is much less developed. This review presents the recent advancement of transition metal-catalyzed asymmetric fluorination reactions, in which the final C-F bond is from reductive elimination of organometallic complexes. In addition, the perspective of the field is also provided for the future studies of asymmetric fluorinations and the related transformations, such as trifluoromethylation, trifluoromethylthiolation and trifluoromethoxylation.
- Subjects
TRANSITION metal catalysts; FLUORINATION; ASYMMETRIC synthesis; REDUCTIVE elimination (Chemistry); CHEMICAL bonds; ORGANOMETALLIC compounds; ORGANIC synthesis
- Publication
Chinese Journal of Chemistry, 2017, Vol 35, Issue 12, p1781
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.201700489