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- Title
Copper Nanoparticles on Controlled Pore Glass and TEMPO for the Aerobic Oxidation of Alcohols.
- Authors
Ibrahem, Ismail; Iqbal, Muhammad Naeem; Verho, Oscar; Eivazihollagh, Alireza; Olsén, Peter; Edlund, Håkan; Tai, Cheuk‐Wai; Norgren, Magnus; Johnston, Eric V.
- Abstract
Herein, we report on the facile synthesis of a heterogeneous copper nanocatalyst and its combination with 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) for the aerobic oxidation of alcohols to their corresponding carbonyl compounds. This low cost copper nanocatalyst was found to exhibit excellent recyclability, making it a highly attractive catalytic system from an economical and environmental point of view. Extensive characterization of the catalyst by a number of techniques revealed that it was comprised of well-dispersed Cu(I/II) nanoparticles with an average size of around 6 nm.
- Subjects
CHEMICAL synthesis; OXIDATION-reduction reaction; NANOPARTICLE synthesis; CARBONYL compounds; TETRAMETHYL compounds
- Publication
ChemNanoMat, 2018, Vol 4, Issue 1, p71
- ISSN
2199-692X
- Publication type
Article
- DOI
10.1002/cnma.201700309