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- Title
Alkylation of C-Phosphorylated Acetimidates Containing an Activated Methylene Group.
- Authors
Shishkin, V. E.; Mednikov, E. V.; Anishchenko, O. V.
- Abstract
N-substituted dialkoxyphosphorylacetimidates, the methylene group located between the phosphoryl and imide groups exhibits substantial CH acidity. One methylene hydrogen atom is replaced in the reactions of these imidates with sodium metal or sodium alcoholates. The sodium derivatives react with alkyl halides to form the corresponding homologs of N-substituted dialkoxyphosphorylacetimidates.
- Subjects
CARBENES; IMIDES; HYDROGEN; ATOMS; SODIUM; ALKALI metals
- Publication
Russian Journal of General Chemistry, 2005, Vol 75, Issue 3, p375
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1007/s11176-005-0234-x