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- Title
Photo‐activated shape memory polymer with chiral twisting based on anisotropic bilayer thin sheets.
- Authors
Tian, Guangming; Zhang, Jie; Li, Mingcai; Zhang, Xin; Yang, Dong; Zheng, Shuguang
- Abstract
The remotely controlled shape memory behaviors of a two‐dimensional (2D) sheet to controlled helix structure upon external stimuli is of great significance in the field of smart materials. Herein, we devise a strategy to fabricate a series of shape memory polycaprolactone/W18O49 nanowire film via highly efficient UV‐triggered thiol‐acrylate click chemistry. The resultant polymer composites exhibited desirable photothermal transfer efficiency and can enable rapid temperature increase over the melting temperature of polymeric matrix, thus remotely actuating shape transformation within 8 s. Owing to the well‐defined architecture of the polymer network, the fabricated elastic composite film exhibited a high degree of crystallinity and showed excellent shape memory properties with Rf of 93.12% and Rr of 95.32%. Remarkably, under a 160 mW/cm2 simulated sunlight illumination, the transformation of flat 2D film into 3D chiral actuators is driven by designing anisotropic bilayer thin sheet, and it yields right‐ and left‐handed helix. This work will pave the way for designing biomimetic flexible actuators toward multifunctional shape‐shifting devices. Highlights: Shape memory polycaprolactone/W18O49 nanowires composite film is fabricated via UV‐triggered thiol‐ene click chemistry.Polymer composites exhibit light‐activated shape memory behaviors.The composite films show excellent shape fixity and shape recovery ratio based on the well‐defined network.The shape morphing behaviors of a flexible 2D bilayer strip into 3D chiral actuators are achieved.
- Subjects
SHAPE memory polymers; SMART materials; POLYMER networks; CLICK chemistry; 3-D films
- Publication
Polymer Engineering & Science, 2023, Vol 63, Issue 12, p4274
- ISSN
0032-3888
- Publication type
Article
- DOI
10.1002/pen.26523