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- Title
Vicinal Functionalization of N-Alkoxyenamines: Tandem Umpolung Phenylation-Nucleophilic Addition Reaction Sequence.
- Authors
Sato, Shohei; Takeda, Norihiko; Miyoshi, Tetsuya; Ueda, Masafumi; Miyata, Okiko
- Abstract
The vicinal functionalization of N-alkoxyenamines, derived in situ from aldehydes and isoxazolidines, has been achieved with the formation of two new carbon-carbon bonds by utilizing an organo-aluminum reagent and subsequent allylmagnesium bromide or tributyltin cyanide as external carbon-centered nucleophiles. By changing the second carbon nucleophile, various amine derivatives were obtained in good yields.
- Subjects
UMPOLUNG; ORGANIC chemistry; NUCLEOPHILIC addition (Chemistry); ADDITION reactions; ALDEHYDES
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 18, p3899
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201500308