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- Title
Synthesis of 3-Substituted 2-Aminonaphtho[2,3- b]furan-4,9-diones from 2-Hydroxy-1,4-Naphthoquinone and Nitroalkenes.
- Authors
Zanwar, Manoj R.; Kavala, Veerababurao; Gawande, Sachin D.; Kuo, Chun‐Wei; Kuo, Ting‐Shen; Chen, Mei‐Ling; He, Chiu‐Hui; Yao, Ching‐Fa
- Abstract
The efficient base-catalyzed synthesis of 3-substituted 2-aminonaphtho[2,3- b]furan-4,9-dione derivatives from readily available precursors such as 2-hydroxy-1,4-naphthoquinone and nitroalkenes under aqueous conditions is described. Interesting features of this methodology are the conversion of a nitro functionality into an amino functionality in the absence of a reducing agent and the development of a three component reaction for accessing the same product from an aldehyde, 2-hydroxy-1,4-naphthoquinone and nitromethane.
- Subjects
NITROALKENES; NITRO compounds; NAPHTHOQUINONE; NAPHTHALENE; ALDEHYDES
- Publication
European Journal of Organic Chemistry, 2013, Vol 2013, Issue 36, p8288
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201300996